-
carbenes in
terms of its reactivity.
Typical reactions of in situ
generated zirconocenes are
coupling or
insertion to form metallacycles.
These reactions have...
-
Zirconocene dichloride is an
organozirconium compound composed of a
zirconium central atom, with two
cyclopentadienyl and two
chloro ligands. It is a...
-
compound with the
formula (C5H5)2ZrHCl,
sometimes called zirconocene hydrochloride or
zirconocene chloride hydride, and is
named after Jeffrey Schwartz,...
-
Frank G.; Burlakov,
Vladimir V. (2000-02-01). "What Do Titano- and
Zirconocenes Do with
Diynes and Polyynes?".
Accounts of
Chemical Research. 33 (2):...
- compounds, such as
zirconium dioxide, and
organometallic compounds, such as
zirconocene dichloride. Five
isotopes occur naturally, four of
which are stable....
- 1021/cr00089a004. Rosenthal, U.; et al. (2000). "What Do Titano- and
Zirconocenes Do with
Diynes and Polyynes?".
Chemical Reviews. 33 (2): 119–129. doi:10...
-
Prize in
Chemistry to Ei-Ichi Negishi. The
foremost applications of
zirconocenes involve their use as
catalysts for
olefin polymerization. Schwartz's...
-
titanocene dichloride. In
combination with 20 to 100 mol % Cp2ZrCl2 (
zirconocene dichloride), the (CH3)2Al-CH3 adds "across"
alkynes to give
vinyl aluminium...
- 2-position of pyridine.
Halophosphorines do
undergo noble-metal- or
zirconocene-catalyzed substitution, and λ5-phosphorines
exhibit a much more traditional...
- seven-membered ring in a
trans conformation. Once this
conformation is achieved,
zirconocene-mediated
cyclization of
Structure 5 can occur, and
oxidizing the resulting...
