Definition of Ynolates. Meaning of Ynolates. Synonyms of Ynolates

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Definition of Ynolates

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Meaning of Ynolates from wikipedia

- tautomerize to ketenes. The deprotonated anions of ynols are known as ynolates, the triple-bond analogues to enolates. Alkynols may be formed by the alkynylation...
- nucleophilic site on enolates is delocalized onto both carbon and oxygen sites. Ynolates are also unsaturated alkoxides derived from acetylenic alcohols. Phenoxides...
- Kowalski, C. J. (1993). "Ethyl 1-Naphthylacetate: Ester Homologation Via Ynolate Anions". Organic Syntheses. 71: 146. doi:10.15227/orgsyn.071.0146. Huggett...
- 5, ketenyl anion has two major resonance structures: ketenyl form and ynolate form. Due to the resonance structures, alkali metal cations can be coordinated...
- Has been used to convert β-amino esters from α-amino esters through an ynolate intermediate. Seyferth–Gilbert homologation in which an aldehyde is converted...
- Kowalski, C. J. (1993). "Ethyl 1-Naphthylacetate: Ester Homologation Via Ynolate Anions". Organic Syntheses. 71: 146; Collected Volumes, vol. 9, p. 426...
- contributed extensively to the synthesis of β-lactams using alkenyl anions, ynolates, novel isocyanates, iron vinylidines, heteroatom functionalized nitroalkenes...
- highly stereoselective synthesis of tri- and tetrasubstituted olefins via ynolates". Tetrahedron Lett. 39 (27): 4857–4860. doi:10.1016/s0040-4039(98)00921-6...
- Kowalski, C. J. (1993). "Ethyl 1-naphthylacetate: ester homologation via ynolate anions". Organic Syntheses. 71: 146; Collected Volumes, vol. 9, p. 426...