-
Xantphos is an
organophosphorus compound derived from the
heterocycle xanthene. It is used as a
bidentate diphosphine ligand and is
noteworthy for having...
-
diphenyl ether (DPE)
which makes up the ligand's backbone. It is
similar to
Xantphos,
another diphosphine ligand, but is more
flexible and has a
smaller bite...
- halides.
Xantphos is
sometimes classified as a trans-spanning ligand, with less
steric bulk
compared to TRANSPHOS.
SPANphos is
comparable to
XANTPHOS but more...
- space. One way of
doing this is to use a
trans spanning ligand such as
Xantphos. As
these metal complexes traditionally form
square planar geometries,...
- 3-Bis(diphenylphosphino)butane
BINAP 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 93
Xantphos 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene 108 DPEphos...
-
irreversible in the
formation of
linear aldehydes. Furthermore,
studies using Xantphos ligands (ligands with
bulky backbones) in
hydroformylation have indicated...
- N-heterocyclic
carbene ligands and
ligands with wide bite
angles such as
Xantphos and
Spanphos which also have been
developed considerably.) The
first generation...
- (dppe) and 1,1'-Bis(diphenylphosphino)ferrocene, the
trans spanning xantphos and spanphos. The
complex dichloro(1,3-bis(diphenylphosphino)propane)nickel...
-
partial hydrolysis leading to the one-dimensional
coordination polymer [{Cu(
xantphos)(μ-PO2F2)}n]".
Inorganic Chemistry Communications. 58: 64–66. doi:10.1016/j...
- J.
Louie "Synthesis,
Mechanism of Formation, and
Catalytic Activity of
Xantphos Nickel p-Complexes" Chem. Commun. 2014, 50, 15577-15580. A. Thakur, M....
