-
XPhos is a
phosphine ligand derived from biphenyl. Its
palladium complexes exhibit high
activity for Buchwald-Hartwig
amination reactions involving aryl...
- a
removable byproduct.
XPhos supports Pd-based
catalysts for
amination and
amidation of
arylsulfonates and aryl halides.
XPhos has also been used in the...
-
ligand has
convenient handling characteristics since it is air-stable.
XPhos CPhos Suzuki reaction Barder, T.E.; Walker, S.D.; Martinelli, J.R.; Buchwald...
- L in the
catalyst can be triphenylphosphine, dppe, BINAP,
chiraphos or
XPhos.
Palladium catalysts in
general have
higher chemical yields and
higher functional...
-
elimination of B,
relative to the rate of β-hydride elimination.
Negishi coupling XPhos SPhos Dialkylbiaryl phosphine ligands Han, C.; Buchwald, S. L. (2009). "Negishi...
- tosylhydrazone, an aryl
halide with
catalyst system dibenzylideneacetone /
XPhos. As part of the
catalytic cycle the
diazo intermediateformed by decomposition...
