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Uranocene, U(C8H8)2, is an
organouranium compound composed of a
uranium atom
sandwiched between two
cyclooctatetraenide rings. It was one of the first...
- 8,
abbreviated cot2−),
namely the
lanthanocenes and the
actinocenes (
uranocene and others).
Metallocenes are a
subset of a
broader class of compounds...
- thorocene. It is
isotypic with the better-known
analogous uranium compound uranocene. It can be
prepared by
reacting K2C8H8 with
thorium tetrachloride in tetrahydrofuran...
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group of
Andrew Streitwieser prepared the
stable but
pyrophoric compound uranocene (COT)2U,
which has an atom of
uranium sandwiched between two cyclooctatetraenide...
-
analogous in
structure to
uranocene. There, the
metal atom is
sandwiched between two
cyclooctatetraene ligands.
Similar to
uranocene, it can be
prepared by...
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cyclooctatetraenide Tb(C8H8)2
Protactinocene (Pa(C8H8)2)
Thorocene (Th(C8H8)2)
Uranocene U(C8H8)2
Neptunocene (Np(C8H8)2)
Plutonocene (Pu(C8H8)2)
Cerocene Ce3+(C8H81...
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resulting in the
general formula An(C8H8)2. The most
studied actinocene is
uranocene, U(C8H8)2,
which in 1968 was the
first member of this
family to be synthesised...
-
elements at
elevated temperature.
Organometallic complexes analogous to
uranocene are
known also for
other actinides, such as thorium, protactinium, neptunium...
- not
obvious from the formula. Ferrocene: bis(η5-cyclopentadienyl)iron
Uranocene: bis(η8-1,3,5,7-cyclooctatetraene)uranium W(CO)3(PPri3)2(η2-H2): the first...
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including yttrium, lanthanides, and actinides. The
sandwich compound uranocene (U(COT)2)
features two η8-COT ligands. In bis(cyclooctatetraene)iron (Fe(COT)2)...