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Uranocene, U(C8H8)2, is an
organouranium compound composed of a
uranium atom
sandwiched between two
cyclooctatetraenide rings. It was one of the first...
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group of
Andrew Streitwieser prepared the
stable but
pyrophoric compound uranocene (COT)2U,
which has an atom of
uranium sandwiched between two cyclooctatetraenide...
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independent research career was the
determination of the
crystal structure of
uranocene (di-π-(cyclooctatetraene)uranium). This
structure was a
seminal discovery...
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including yttrium, lanthanides, and actinides. The
sandwich compound uranocene (U(COT)2)
features two η8-COT ligands. In bis(cyclooctatetraene)iron (Fe(COT)2)...
- 8,
abbreviated cot2−),
namely the
lanthanocenes and the
actinocenes (
uranocene and others).
Metallocenes are a
subset of a
broader class of compounds...
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elements in the +4
oxidation state.
Compared to
other actinocenes such as
uranocene,
plutonocene has been
studied to a
lesser degree since the 1980s due to...
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analogous in
structure to
uranocene. There, the
metal atom is
sandwiched between two
cyclooctatetraene ligands.
Similar to
uranocene, it can be
prepared by...
- that is used as a
precursor to
cyclooctatetraenide complexes, such as
uranocene (U(C8H8)2).
Analogs of K2C8H8 are
known with ring substituents, with different...
- thorocene. It is
isotypic with the better-known
analogous uranium compound uranocene. It can be
prepared by
reacting K2C8H8 with
thorium tetrachloride in tetrahydrofuran...
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resulting in the
general formula An(C8H8)2. The most
studied actinocene is
uranocene, U(C8H8)2,
which in 1968 was the
first member of this
family to be synthesised...