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Salts of the
tropylium cation can be stable, even with
nucleophiles of
moderate strength e.g.,
tropylium tetrafluoroborate and
tropylium bromide (see...
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Tropylium tetrafluoroborate is an
organic compound with the
formula [C7H7]+[BF4]β.
Containing the
tropylium cation and the non-coordinating tetrafluoroborate...
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methylene bridge (βCH2β) with
respect to the
other atoms;
however the
related tropylium cation is.
Albert Ladenburg first generated cycloheptatriene in 1881 by...
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incomplete octet of electrons; however,
certain carbenium ions, such as the
tropylium ion, are
relatively stable due to the
positive charge being delocalised...
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selected nucleophiles with
selected electrophilic carbocations such as
tropylium or
diazonium cations: or (not displa****) ions
based on
malachite green...
- or
negative carbanions.
Carbocations are
often named -um.
Examples are
tropylium and
triphenylmethyl cations and the
cyclopentadienyl anion. Haloalkanes...
- of
toluene [1]. Note
parent peak
corresponding to
molecular m**** M = 92 (C7H8+) and
highest peak at M-1 = 91 (C7H7+, quasi-stable
tropylium cation)....
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structure for it; however,
Doering and Knox
convincingly showed that it was
tropylium (cycloheptatrienylium) bromide. This ion is
predicted to be
aromatic by...
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cyclopropenyl cation (2e system), the
cyclopentadienyl anion (6e system), the
tropylium ion (6e), and the
cyclooctatetraene dianion (10e).
Aromatic properties...
- ethenium, C2H+5 (protonated ethene) benzenium, C6H+7 (protonated benzene)
tropylium, C7H+7 (protonated tropylidene)
silylium cations, R3Si+ (protonated silylenes)...