Definition of Trimethylsulfoxonium. Meaning of Trimethylsulfoxonium. Synonyms of Trimethylsulfoxonium

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Definition of Trimethylsulfoxonium

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Meaning of Trimethylsulfoxonium from wikipedia

- Trimethylsulfoxonium iodide is an organosulfur compound with the chemical formula [(CH3)3S=O]+I−. It is a sulfoxonium salt derived from dimethylsulfoxide...
- yield trimethylsulfoxonium iodide. Treated with sodium hydride, trimethylsulfoxonium forms dimethylsulfoxonium methylide. Trimethylsulfoxonium can polymerise...
- nucleophilic toward hard electrophiles. With methyl iodide it forms trimethylsulfoxonium iodide, [(CH3)3SO]+I−: (CH3)2SO + CH3I → [(CH3)3SO]I This salt can...
- (1). Firstly, it is converted to the corresponding oxirane through trimethylsulfoxonium idoide with sodium hydride in DMSO and THF, yielding 2-ethyl-2-phenyl-oxirane...
- groups can be replaced by C-D bonds, using acid or base catalysis. Trimethylsulfoxonium iodide, made from dimethyl sulfoxide and methyl iodide can be recrystallized...
- [(CH3)3S]+I− An extra oxygen atom can bond to the sulfur atom to yield the trimethylsulfoxonium ion [(CH3)3S=O]+, where the sulfur atom is tetravalent and tetracoordinated...
- an amide with 4-fluorobenzylamine, followed by methylation using trimethylsulfoxonium iodide. Use of that reagent ensures the required chemoselectivity...
- Johnson–Corey–Chaykovsky reaction by reaction of canrenone with trimethylsulfoxonium iodide and sodium hydride. Canrenone Mexrenone Prorenoate pot****ium...