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Trimethylsilyldiazomethane is the
organosilicon compound with the
formula (CH3)3SiCHN2. It is
classified as a
diazo compound. Trimethylsilyldiazomethane...
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reduced by the
introduction of the
safer and
equivalent reagent trimethylsilyldiazomethane. For
safety and
convenience diazomethane is
always prepared as...
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methylated with
methyl halides.
Diazomethane and the
safer analogue trimethylsilyldiazomethane methylate carboxylic acids, phenols, and even alcohols: RCO 2...
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reduced by the
introduction of the
safer and
equivalent reagent trimethylsilyldiazomethane. Electrophilic,
soluble alkylating agents are
often toxic and...
- (2007). "Mechanism of
Methyl Esterification of
Carboxylic Acids by
Trimethylsilyldiazomethane". Angew. Chem. Int. Ed. Engl. 46 (37): 7075–7078. doi:10.1002/anie...
- T. (1980). "New
Methods and
Reagents in
Organic Synthesis. 8.
Trimethylsilyldiazomethane. A New, Stable, and Safe
Reagent for the
classical Arndt-Eistert...
- carbon. As
originally developed, an
allyl sulfide reacts with
trimethylsilyldiazomethane to form the
homoallyl sulfide compound. The
reaction was first...
- a [3+2]
cycloaddition reaction between an aryl
diazonium and
trimethylsilyldiazomethane.
There are
several pharmaceutical agents which are tetrazoles...
-
deprotection is
demonstrated in a
photochemical transesterification by
trimethylsilyldiazomethane utilizing the
kinetic isotope effect: Due to this
effect the quantum...
- Shioiri, Takayuki; Aoyama, Toyohik; Mori,
Shigehiro (1990). "
Trimethylsilyldiazomethane".
Organic Syntheses. 68: 1. doi:10.15227/orgsyn.068.0001. Li,...
