-
Triisobutylaluminium (TiBA) is an
organoaluminium compound with the
formula Al(CH2CH(CH3)2)3. This
colorless pyrophoric liquid is
mainly used to make linear...
-
preference to the
alkyl groups.
DIBAL can be
prepared by
heating triisobutylaluminium (itself a dimer) to
induce β-hydride elimination: (i-Bu3Al)2 → (i-Bu2AlH)2...
-
organoaluminium compounds are the
dimer trimethylaluminium, the
monomer triisobutylaluminium, and the titanium-aluminium
compound called Tebbe's reagent. The...
- for branched-chain
alkyls (e.g. Pri, Bui, Me3CCH2); for example,
triisobutylaluminium exists as an
equilibrium mixture of the
monomer and dimer. These...
- (0 °F; 255 K)
Related compounds Related compounds Trimethylaluminium Triisobutylaluminium Except where otherwise noted, data are
given for
materials in their...
-
typically deposited by electroplating.
Aluminium can be
deposited from
triisobutylaluminium (TIBAL) and
related organoaluminium compounds. CVD for molybdenum...
- for branched-chain
alkyls (e.g. Pri, Bui, Me3CCH2); for example,
triisobutylaluminium exists as an
equilibrium mixture of the
monomer and dimer. These...
-
catalyzed by
triphenylchromium tri-tetrahydrofuranate or by a
complex of
triisobutylaluminium and
titanium tetrachloride.
Trimerisation of
three diphenylacetylene...
-
catalyzed by
triphenylchromium tri-tetrahydrofuranate or by a
complex of
triisobutylaluminium and
titanium tetrachloride.
Hexamethylbenzene can be used as a ligand...
-
transformation are trimethylaluminium, triethylaluminium, and
sometimes triisobutylaluminium. When
using trialkylaluminium reagents that have beta-hydrides, eliminations...
