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Trifluoromethylation in
organic chemistry describes any
organic reaction that
introduces a
trifluoromethyl group in an
organic compound. Trifluoromethylated...
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unique transformations on benzene, such as halogenation, cyanation,
trifluoromethylation, and hydroxylation. The
reaction was
discovered in 1884 by Swiss...
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chemical compound used in
organic synthesis for
direct electrophilic trifluoromethylation. Synthesis, properties, and
reactivity of the
compound were first...
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sodium salt of
trifluoroacetic acid. It is used as a
source of
trifluoromethylations. With a pKa of 0.23 for
trifluoroacetic acid, the trifluoroacetate...
- Langlois,
Bernard R.; Laurent, Eliane; Roidot,
Nathalie (1991). "
Trifluoromethylation of
aromatic compounds with
sodium trifluoromethanesulfinate under...
- Qun (2015-01-28). "Trifluoromethyltrimethylsilane:
Nucleophilic Trifluoromethylation and Beyond".
Chemical Reviews. 115 (2): 683–730. doi:10.1021/cr400473a...
- are of some
relevance as pharmaceuticals. One
example is riluzole.
Trifluoromethylation Synthetic Approaches to Trifluoromethoxy-Substituted
Compounds A...
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organocopper and
organocadmium compounds have been
developed as
trifluoromethylation reagents.
Fluoroform is a
precursor of the Ruppert-Prakash reagent...
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diaryliodonium salts as an oxidant. NiIV can
perform challenging trifluoromethylation reactions on (hetero)arenes. A
representative method is
shown below...
- Fuel
Cells for
Wastewater Treatment Recent Advances in
Direct C−H
Trifluoromethylation of N‐Heterocycles The
comparative soil
fertility in
traditional and...
