-
Trichloroethyl chloroformate is used in
organic synthesis for the
introduction of the
trichloroethyl chloroformate (Troc)
protecting group for amines,...
- been used as a
sedative hypnotic. The
hypnotic drug
triclofos (2,2,2-
trichloroethyl phosphate) is
metabolized in vivo to 2,2,2-trichloroethanol. Chronic...
- trichloroethanenitrile, cyanochloroform,
trichloromethyl cyanide,
trichloroethyl nitrile Identifiers CAS
Number 545-06-2 Y 3D
model (JSmol) Interactive...
-
amine protecting groups, such as Boc, Fmoc,
benzyl chloroformate and
trichloroethyl chloroformate are carbamates.
Urethane (ethyl carbamate) was once produced...
-
trichloromethyl phosphine acids,
organic esters of a-acetoxy-b,b,b-
trichloroethyl phosphonic acid,
trichloromethyl esters of
phosphoric acid, trichloromethyl...
- chromatography/m****
spectrometry without and with
derivatization with 2,2,2-
trichloroethyl chloroformate,
liquid chromatography/high-resolution m**** spectrometry...
- methylamine. Too
stable to
readily remove from
aliphatic amides. Troc (
trichloroethyl chloroformate )
group –
Removed by Zn
insertion in the
presence of acetic...
-
trimethyl phosphonoacetate 4. The
hydroxyl group is
activated as a
trichloroethyl carbonate leaving group to 6. Next an
enantioselective Trost AAA reaction...
-
removed in 5.8 (hydrogen
fluoride pyridine) and
replaced by a TROC (
trichloroethyl carbonate,
TROCCl )
group in 5.9. The C13
alcohol protective group was...
-
hydrolysis to give the alcohol,
second esterification to form 2,2,2-
trichloroethyl carbonate and as last epoxidation. Thereafter, the
bisepoxide was oxidized...
