- phase-transfer
catalysts only α-
trichloroacetimidates are
obtained (thermodynamically controlled). The
trichloroacetimidates are
reacted between −40 °C and...
-
trichloroacetimidates provides many
advantages including ease of formation,
reactivity and
stereochemical outcome. O-Glycosyl
trichloroacetimidates are...
- (named
after Larry Overman) is a
Claisen rearrangement of
allylic trichloroacetimidates to
allylic trichloroacetamides. The
Overman rearrangement is applicable...
- in methanol. In the
trichloroacetimidate method of
Richard R. Schmidt, the
peracetylated O-(α-d-glucopyranyl)
trichloroacetimidate forms with 1-octanethiol...
-
Bucher et al.
provides a way to
utilize a
fluoro oxonium ion and the
trichloroacetimidate to
encourage B
stereoselectivity through the
gauche effect. This...
-
synthesis are
glycosyl halides,
glycosyl acetates, thioglycosides,
trichloroacetimidates,
pentenyl glycosides, and glycals. Of all
these donors, glycosyl...
-
method for the
synthesis of
amines by the
rearrangement of
allylic trichloroacetimidates. 1,3
Transposition of
alcohol and
amine functions". J. Am. Chem...
-
promoter or catalyst: The
bromide can be
activated by
silver salts, the
trichloroacetimidate with acid catalysis, and
thioglycosides with N-iodosuccinimide/triflic...
-
catalyzed reaction of
benzyl alcohol upon
trichloroacetonitrile yields a
trichloroacetimidate. This
species has
orthogonal stability to
acetate and TBS protections...
- p-methoxybenzyl
halide (chloride or bromide) 4-methoxybenzyl-2,2,2-
trichloroacetimidate can be used to
install the PMB
group in
presence of:
Scandium (III)...
