-
reducing agent and the base. The
byproducts are
acetonitrile (6) and the
trialkylphosphine oxide (8). The
Mitsunobu reaction has been
applied in the synthesis...
- P(CH2CH2CN)3. It is
white solid that is air stable,
which is
unusual for a
trialkylphosphine. It is
prepared by the
hydrophosphination of
acrylonitrile with phosphine...
- metal.
Continuing with this analogy, NHCs are
often compared with
trialkylphosphine ligands. Like phosphines, NHCs
serve as
spectator ligands that influence...
-
phosphorus center with a P-Te bond
length of 236 picometers.
Simple trialkylphosphine tellurides are pale
yellow solids.
Phosphine tellurides like trioctylphoshine...
-
sodium azide. The
azido alcohol is then
reduced with the use of a
trialkylphosphine such as
triphenylphosphine in a
manner similar to the
Staudinger reaction...
-
metal centers.
Examples include cis-WCl4(OPPh3)2 and NbOCl3(OPPh3)2
Trialkylphosphine oxides are more
basic (better ligands) than
triarylphosphine oxides...
-
instead of NiBr2. S****
developed cobalt-based
catalysts modified with
trialkylphosphine ligands for
hydroformylation (now a
rhodium catalyst is more commonly...
-
cheaper and less air-sensitive than
trimethylphosphine and
other trialkylphosphines.
Although its
complexes are
generally highly soluble, they are often...
- Day,
Victor W. (1981-07-01). "Quadruply
bonded tetramethyltetrakis(
trialkylphosphine)dimolybdenum compounds:
phosphine exchange kinetics,
acetone formation...
-
composed of Ti, C and S. With
trialkylphosphines, the
cycle dimerize into
rings of
various sizes,
depending on the
trialkylphosphine used. Shaver, Alan; McCall...
