-
Transmetalation (alt. spelling: transmetallation) is a type of
organometallic reaction that
involves the
transfer of
ligands from one
metal to another...
-
mechanism of
transmetalation for the
Suzuki coupling remains to be discovered. The
organoboron compounds do not
undergo transmetalation in the absence...
- the
conventional method from the
alkyl halide and Mg. The
reductive transmetalation achieves:
AdZnBr + Mg →
AdMgBr + Zn
Because Grignard reagents are so...
-
addition of a
halide or
pseudohalide (2) to a
palladium catalyst (1),
transmetalation of 3 with an
organotin reagent (4), and
reductive elimination of 5...
-
vinyllithium through transmetalation with n-BuLi.
Organolithium can also be used in to
prepare organozinc compounds through transmetalation with zinc salts...
-
Organoboron chemistry or
organoborane chemistry studies organoboron compounds, also
called organoboranes.
These chemical compounds combine boron and carbon;...
- ethyllithium.
Transmetalation involves the
exchange of two
metals between organic molecules by a
redox exchange mechanism. For example,
transmetalations often...
-
Retrieved 18
February 2017. Dieter, R. K.; Watson, R. T. (2009). "
Transmetalation reactions producing organocopper compounds". In Rappoport, Z.; Marek...
- (CH3)2HCMgCl This
reagent is used to
prepare other Grignard reagents by
transmetalation. An
illustrative reaction involves the
generation of the
Grignard reagent...
- 9003A. doi:10.1021/ja00207a003. Dieter, R. K.; Watson, R. T. (2009). "
Transmetalation reactions producing organocopper compounds". In Rappoport, Z.; Marek...
