- In
organic chemistry, a
toluenesulfonyl group (tosyl group,
abbreviated Ts or Tos) is a
univalent functional group with the
chemical formula −SO2−C6H4−CH3...
-
aluminium hydride: 4 CH3C6H4SO2OR + LiAlH4 → LiAl(O3SC6H4CH3)4 + 4 RH Thus,
tosylation followed by
reduction allows for
removal of a
hydroxyl group. Likewise...
- elimination.
Reduction of
tosylate esters gives the hydrocarbon. Thus,
tosylation followed by
reduction allows for the
deoxygenation of alcohols. In a famous...
-
Diaziridines can be
prepared from
ketones by oximation,
followed by
tosylation (or mesylation), and then
finally by
treatment with
ammonia (NH3). Generally...
-
trifluorotoluene is
similar to
dichloromethane in
standard acylation,
tosylation, and
silylation reactions. The
dielectric constants for dichloromethane...
-
organic chemistry, such as nitration, esterification, etherification,
tosylation, etc., and
converted into
compounds with
interesting properties or into...
-
reactions for
diols and polyol. DBTO has been used in the
regioselective tosylation (a
specific type of sulfonation) of
certain polyols to
selectively tosylate...
- 5-dicarbonyl unit in MeOH
using pyrrolidine acetate as the base,
followed by
tosylation of the oxime's
hydroxyl group,
afforded the
cyclohexenone derivative H-26...
-
protection (Me2SiHCl, imidazole) and
oxidation (DDQ) to DMS
ether 23,
tosylation (TsCl, DMAP) to 24,
deprotection to diol (TBAF) and
reprotection (TMSOTf...
- that can then be
purified using recrystallization. The
final step is
tosylation and
alkylation of the
alcohol which gives (+)-cis-7,8-epoxy-2-methyloctadecane...
