Definition of Torquoselective. Meaning of Torquoselective. Synonyms of Torquoselective

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Definition of Torquoselective

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Meaning of Torquoselective from wikipedia

- In stereochemistry, torquoselectivity is a special kind of stereoselectivity observed in electrocyclic reactions, defined as "the preference for inward...
- causing the product to be cis-dimethylcyclohexadiene. In addition, the torquoselectivity in an electrocyclic reaction refers to the direction of rotation....
- enantioselective synthesis of (−)-pinoresinol. Dynamic stereochemistry Torquoselectivity Regioselectivity Chemoselectivity (a)"Overlap Control of Carbanionoid...
- cyclization. Almost all of the attempts are based on the idea of torquoselectivity; selecting one direction for the vinyl groups to "rotate" in turn...
- recognized as conrotatory. Woodward's rules for calculating UV absorptions Torquoselectivity The principle of orbital symmetry conservation is generally credited...
- disrotatory. In this ring opening reaction, there is an issue of torquoselectivity. Electronegative substituents prefer to rotate outwards, to the same...
- closure step is rate-determining, stereochemical predictions based on torquoselectivity are reliable. Other factors that affect the stereochemistry include...