Definition of TmsCl. Meaning of TmsCl. Synonyms of TmsCl

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Definition of TmsCl

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Meaning of TmsCl from wikipedia

- organosilicon compound (silyl halide), with the formula (CH3)3SiCl, often abbreviated Me3SiCl or TMSCl. It is a colourless volatile liquid that is stable in the...
- reactions. In organic synthesis, TMS group is used as a protecting group for alcohols. Trimethylsilyl chloride (TMSCl) or trimethylsilyl trifluoromethanesulfonate...
- cyanoborohydride is often done in the presence of trimethylsilyl chloride, or TMSCl. Sodium cyanoborohydride can be purchased from most chemical suppliers....
- very efficient and replaced TMSCl reagent. Silylation of glutamic acid with excess hexamethyldisilazane and catalytic TMSCl in either refluxing xylene...
- with a covalent M-O(SO2CF3) bond, the by-product being the highly volatile TMSCl which is easily removed. Joseph Sweeney; Gemma Perkins; Enrique Aguilar;...
- RCONR'2 + Litms → RC(O)tms + LiNR'2 Acid chlorides are converted using hexamethyldisilane: RCOCl + tms−tms → RC(O)tms + tmsCl Some acyl silanes are prepared...
- pyridine in dichloromethane HBr and acetic acid at 70 °C Refluxing with TMSCl, sodium iodide and acetonitrile Reduction with SmI2 Reduction with Red-Al...
- reagent with trimethylsilyl chloride (tms = (CH3)3Si): 2 Na2Fe(CO)4 + 4 tmsCl → Fe2(CO)6C4(Otms)4 + 2 CO + 4 NaCl (warning: unbalanced reaction !) Some...
- intermidate further confirmed the mechanism. IrCl(CO)(PPh3)2 + CH2=C(CH2Cl)(CH2tms) → η4-[C(CH2)3]IrCl(PPh3)(CO) + tmsCl + PPh3 (Ph = C6H5) According to gas phase...
- 189502801248. Izumi, Minoru; ****ase, Koichi; Kusumoto, Shoichi (2002). "TMSCl as a mild and effective source of acidic catalysis in Fischer glycosidation...