-
cyclic thiosulfinates containing the 1,2-dithiolane-1-oxide ring,
isolated from the
tropical weed
Sphenoclea zeylanica.
These heterocyclic thiosulfinates are...
-
compounds serve as the
precursors of
several thiosulfinates such as S-(2-hydroxyethyl) 2-hydroxyethane)
thiosulfinate, S-(2-hydroxylethyl) phenylmethanethiosulfinate...
- to
cleave the sulfur-containing
compound alliin to
release reactive thiosulfinates.
These then
react with each
other and with
amino acids found naturally...
-
which is
responsible for the
aroma of
fresh garlic.
Allicin and
other thiosulfinates in
garlic are
unstable and form a
number of
other compounds, such as...
- odor. It is a
thioester of
sulfenic acid. It is also
known as
allyl thiosulfinate. Its
biological activity can be
attributed to both its
antioxidant activity...
- ("sulfide oxide"), a sulfone, R−S(O)2−R, is the S,S-dioxide of a sulfide, a
thiosulfinate, R−S(O)−S−R, is the S-oxide of a disulfide, and a thiosulfonate, R−S(O)2−S−R...
- to
chemical substances.
Substances such as piperine, capsaicin, and
thiosulfinates can
cause a
burning or
tingling sensation by
inducing a
trigeminal nerve...
-
lachrymatory agent (Z)-butanethial S-oxide,
along with
several 1-butenyl
thiosulfinates are
detected by m****
spectrometry using a DART ion source. (Z)-Butanethial...
-
Spectrometry in
Allium Chemistry. (Z)-Butanethial S-Oxide and 1-Butenyl
Thiosulfinates and
their S-(E)-1-Butenylcysteine S-Oxide
Precursor from
Allium siculum"...
- Cl2 -> 2 ArSCl}}} More unusually,
oxidation of
disulfides gives first thiosulfinates and then thiosulfonates: RSSR + [O] → RS(=O)SR RS(=O)SR + [O] → RS(=O)2SR...
