Definition of Thiosulfinate. Meaning of Thiosulfinate. Synonyms of Thiosulfinate

Here you will find one or more explanations in English for the word Thiosulfinate. Also in the bottom left of the page several parts of wikipedia pages related to the word Thiosulfinate and, of course, Thiosulfinate synonyms and on the right images related to the word Thiosulfinate.

Definition of Thiosulfinate

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Meaning of Thiosulfinate from wikipedia

- In organosulfur chemistry, thiosulfinate is a functional group consisting of the linkage R-S(O)-S-R (R refers to organic substituents). Thiolsulfinates...
- odor. It is a thioester of sulfenic acid. It is also known as allyl thiosulfinate. Its biological activity can be attributed to both its antioxidant activity...
- well as oxidation with hydrogen peroxide or peracetic acid giving the thiosulfinate compound, methyl methanethiosulfinate (CH3S(O)SCH3). DMDS is used as...
- compounds serve as the precursors of several thiosulfinates such as S-(2-hydroxyethyl) 2-hydroxyethane)thiosulfinate, S-(2-hydroxylethyl) phenylmethanethiosulfinate...
- ("sulfide oxide"), a sulfone, R−S(O)2−R, is the S,S-dioxide of a sulfide, a thiosulfinate, R−S(O)−S−R, is the S-oxide of a disulfide, and a thiosulfonate, R−S(O)2−S−R...
- Cl2 -> 2 ArSCl}}} More unusually, oxidation of disulfides gives first thiosulfinates and then thiosulfonates: RSSR + [O] → RS(=O)SR RS(=O)SR + [O] → RS(=O)2SR...
- Thioether Sulfonium Thia-crown ether Persulfide Disulfide Sulfenic acid Thiosulfinate Sulfoxide Thiosulfonate Sulfinic acid Sulfone Sulfonic acid Thioketone...
- enantioselective oxidation of inexpensive di-tert-butyl disulfide to the thiosulfinate followed by disulfide bond cleavage by lithium amide. In the original...
- ester through a 6-membered cyclic transition state yields the alkene. Thiosulfinates can eliminate in the manner analogous to sulfoxides. Representative...
- mainly in ****an. These efforts led to the discovery of allicin (diallyl thiosulfinate) in garlic, which became a model for medicinal chemistry efforts to...