- In
organosulfur chemistry,
thiosulfinate is a
functional group consisting of the
linkage R-S(O)-S-R (R
refers to
organic substituents). Thiolsulfinates...
- odor. It is a
thioester of
sulfenic acid. It is also
known as
allyl thiosulfinate. Its
biological activity can be
attributed to both its
antioxidant activity...
- well as
oxidation with
hydrogen peroxide or
peracetic acid
giving the
thiosulfinate compound,
methyl methanethiosulfinate (CH3S(O)SCH3). DMDS is used as...
-
compounds serve as the
precursors of
several thiosulfinates such as S-(2-hydroxyethyl) 2-hydroxyethane)
thiosulfinate, S-(2-hydroxylethyl) phenylmethanethiosulfinate...
- ("sulfide oxide"), a sulfone, R−S(O)2−R, is the S,S-dioxide of a sulfide, a
thiosulfinate, R−S(O)−S−R, is the S-oxide of a disulfide, and a thiosulfonate, R−S(O)2−S−R...
- Cl2 -> 2 ArSCl}}} More unusually,
oxidation of
disulfides gives first thiosulfinates and then thiosulfonates: RSSR + [O] → RS(=O)SR RS(=O)SR + [O] → RS(=O)2SR...
-
Thioether Sulfonium Thia-crown
ether Persulfide Disulfide Sulfenic acid
Thiosulfinate Sulfoxide Thiosulfonate Sulfinic acid
Sulfone Sulfonic acid Thioketone...
-
enantioselective oxidation of
inexpensive di-tert-butyl
disulfide to the
thiosulfinate followed by
disulfide bond
cleavage by
lithium amide. In the original...
-
ester through a 6-membered
cyclic transition state yields the alkene.
Thiosulfinates can
eliminate in the
manner analogous to sulfoxides. Representative...
-
mainly in ****an.
These efforts led to the
discovery of
allicin (diallyl
thiosulfinate) in garlic,
which became a
model for
medicinal chemistry efforts to...
