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Thiophosphates (or phosphorothioates, PS) are
chemical compounds and
anions with the
general chemical formula PS 4−xO3− x (x = 0, 1, 2, or 3) and related...
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Phosphates may
contain sulfur in
place of one or more
oxygen atoms (
thiophosphates and organothiophosphates).
Orthophosphates are
especially important...
- classically,
thiophosphates would include a P=S
double bond as
illustrated by malathion. The
terminology is used
loosely and
thiophosphates include P-S...
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thiophosphate. Here the
sulfur in
dimethyl thiophosphate attacks on one of the
oxygens of thiodiglycol. One of the
oxygens of
dimethyl thiophosphate in...
- David; Hils, John (18
December 2013). "Phosphate Esters,
Thiophosphate Esters and
Metal Thiophosphates as
Lubricant Additives". Lubricants. 1 (4): 132–148...
- alcohols.
Phosphoryl thioates are
thermodynamically much
stabler than
thiophosphates,
which can
rearrange at high
temperature or with a
catalytic alkylant...
-
Chemomechanical Processes in Nickel-Rich
Layered Oxide Cathodes and
Lithium Thiophosphate Solid Electrolytes".
Chemistry of Materials. 29 (13): 5574–5582. doi:10...
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deactivates the molecule,
occurs at the aryl
ester bond
resulting in
diethyl thiophosphate and 4-nitrophenol. (C2H5O)2P(S)OC6H4NO2 + H2O → HOC6H4NO2 + (C2H5O)2P(S)OH...
- as the
hydrated solid or as an
aqueous solution together with
other thiophosphates such as
sodium monothiophosphate and
sodium trithiophosphate. It is...
- rare, easy
oligomerization P
diphosphenes common compounds such as
thiophosphates and
phosphine sulfides, for example,
triphenylphosphine sulfide and...