-
Thiophosgene is a red
liquid with the
formula CSCl2. It is a
molecule with
trigonal planar geometry.
There are two
reactive C–Cl
bonds that
allow it to...
- Often,
thiocarbonyldiimidazole is used
instead of
thiophosgene as
shown above,
since thiophosgene has a
similar toxicity profile as phosgene, whereas...
-
commercially available but can also be
prepared via the
reaction of
thiophosgene with two
equivalents of imidazole. The
imidazole groups on TCDI can be...
-
contaminating the Ohio River.
Carbonyl bromide Carbonyl fluoride Oxalyl chloride Thiophosgene Thionyl chloride Perfluoroisobutene Bis(trifluoromethyl)
disulfide Merck...
- inhalation. TFD can be
produced by
reaction of
perchloromethyl mercaptan or
thiophosgene with
sodium fluoride. TFD is
extremely toxic by inhalation. TFD is a...
- Cl2 → CCl4 + S2Cl2 This
conversion proceeds via the
intermediacy of
thiophosgene, CSCl2. CS2 is a
ligand for many
metal complexes,
forming pi complexes...
- S2Cl2 also
arises from the
chlorination of CS2 as in the
synthesis of
thiophosgene or
carbon tetrachloride. S2Cl2
hydrolyzes to
sulfur dioxide and elemental...
-
compounds react to give phosgene:
Reaction with
hydrogen sulfide gives thiophosgene: CCl4 + H2S → CCl2S + 2 HCl
Carbon tetrachloride was
originally synthesized...
- 4,4-tetrachloro-1,3-dithietane, the photochemically-formed
dimer of
thiophosgene, and tetrakis(trifluoromethyl)-1,3-dithietane, [(CF3)2CS]2. Oxidized...
-
include the
important compounds carbon disulfide,
carbonyl sulfide, and
thiophosgene.
Thioketones (RC(=S)R′) are
uncommon with
alkyl substituents, but one...
