-
blend of "thio-" with "alcohol". Many
thiols have
strong odors resembling that of garlic,
cabbage or
rotten eggs.
Thiols are used as
odorants to ****ist in...
-
biochemistry labwork,
thiols such as β-mercaptoethanol (β-ME) or
dithiothreitol (DTT)
serve as
reductants through thiol-disulfide exchange. The
thiol reagents are...
-
carbonylation of
alkynes and
alkenes in the
presence of
thiols.
Thioesters hydrolyze to
thiols and the
carboxylic acid: RC(O)SR' + H2O → RCO2H + RSH The...
-
propagation is the rate-limiting step. The
thiol's hydrogen affinity also
affects the rate-limiting step.
Alkyl thiols have less
abstractable protons and therefore...
-
bonding in
thiols is not prominent.
Aliphatic thiols form
monolayers on gold,
which are
topical in nanotechnology.
Certain aromatic thiols can be accessed...
- OSTEMER. The OSTE
resins are
cured via a
rapid thiol-ene "Click"
reaction between thiols and allyls. The
thiols and
allyls react in a
perfectly alternating...
- 2008-02-29 at the
Wayback Machine Norell, John; Louthan,
Rector P. (1988). "
Thiols". Kirk-Othmer
Concise Encyclopedia of
Chemical Technology (3rd ed.). New...
-
nucleophiles such as
thiols. The
resulting thioether features a
strong C–S bond and the
reaction is
virtually irreversible.
Reaction with
thiols occur in the...
- disulfide,
diethyl disulfide: 2 EtSH + H2O2 → EtS-SEt + 2 H2O Like
other thiols, it
behaves comparably to
hydrogen sulfide. For example, it binds, concomitant...
- Oshima, Koichiro; Utimoto,
Kiitiro (1987). "Et3B
induced radical addition of
thiols to acetylenes".
Chemistry Letters. 16 (8): 1647–1650. doi:10.1246/cl.1987...
