- In
organosulfur chemistry, a
thioketal is the
sulfur analogue of a
ketal (R2C(OR)2), with one of the
oxygen replaced by
sulfur (as
implied by the thio-...
- The
Mozingo reduction, also
known as
Mozingo reaction or
thioketal reduction, is a
chemical reaction capable of
fully reducing a
ketone or
aldehyde to...
- reaction,
gives the
synthetic equivalent of an acyl anion.
Mozingo reduction Thioketal IUPAC,
Compendium of
Chemical Terminology, 2nd ed. (the "Gold Book") (1997)...
- environment. A
laboratory scale hydrogenolysis is the
desulfurization of
thioketals by
Raney nickel. In such cases, the
hydrogen is
contained within the reagent...
- 15227/orgsyn.021.0036. S. R. Wilson, G. M.
Georgiadis (1990). "Mecaptans from
Thioketals:
Cyclododecyl Mercaptan".
Organic Syntheses;
Collected Volumes, vol. 7...
-
compounds of type R1R2C(SR)(SR') (R,R' ≠ H, also
known as
thioacetal and
thioketals.
Hemiaminal Orthoformate IUPAC,
Compendium of
Chemical Terminology, 2nd...
-
involves a 1,2
nucleophilic addition. This reaction, the
formation of a
thioketal,
transforms the
enzyme from its
inactive to
active state.
Inhibition of...
-
intermediate shown at
lower left in the figure,
which has the form of a hemi
thioketal. In the next step, as TPP
departs as a
leaving group,
taking electrons...
-
reduction can be emplo**** when
formation of the
hydrazone fail,
including thioketal reduction with
Raney nickel or
reaction with
sodium triethylborohydride...
- by
action of
elemental sulfur and
aluminium chloride.
Thioacetals and
thioketals feature C−S−C−S−C bond sequence. They
represent a
subclass of sulfides...
