- alkylation,
sulfides bind to
metals to form
thioether complexes. Consequently,
Lewis acids do not
decompose thioethers as they do ethers.
Sulfides are soft ligands...
-
hydrochloric acid.
Thioether complexes feature pyramidal sulfur centers.
Typical C-S-C
angles are near 99° in both free
thioethers and
their complexes...
- substituents.
Sulfones are
typically prepared by
organic oxidation of
thioethers,
often referred to as sulfides.
Sulfoxides are
intermediates in this route...
- an
organosulfur compound with the
formula (CH3)2S. It is the
simplest thioether and has a
characteristic disagreeable odor. It is a
flammable liquid that...
-
aurous ion, is the most
common oxidation state with soft
ligands such as
thioethers, thiolates, and organophosphines. Au(I)
compounds are
typically linear...
- Chao;
Sheng Han;
Xingguo Cheng; Tian**** Ren (2005). "Distribution of
Thioethers in
Hydrotreated Transformer Base Oil by
Oxidation and ICP-AES Analysis"...
- Rhodium(III) also
forms a
range of
complexes with soft
Lewis bases, such as
thioethers, phosphines, and arsines. Such
ligands form Rh(III) complexes, but unlike...
-
products being phosphonium salts.
Thiols are
readily alkylated to give
thioethers via the thiol-ene reaction. The
reaction is
typically conducted in the...
-
unhairing agent in the
liming operation.
Alkylation of
sodium sulfide give
thioethers: Na2S + 2 RX → R2S + 2 NaX Even aryl
halides parti****te in this reaction...
- Baeyer-Villiger oxidation. They are also used for the
oxidation of
amines and
thioethers to
amine oxides and sulfoxides. The
laboratory applications of the valued...
