- best-known
thioesters are
derivatives of
coenzyme A, e.g., acetyl-CoA. The R and R'
represent organyl groups, or H in the case of R. One
route to
thioesters involves...
-
synthesis of
peptide thioesters by Fmoc
chemistry SPPS. Fmoc
chemistry solid phase peptide synthesis techniques for
generating peptide-
thioesters are
based on...
-
unusual pentathiepin ring (5-sulfur
chain cyclised onto a
benzene ring).
Thioesters have
general structure R−C(O)−S−R. They are
related to
regular esters...
-
reaction and in the Rauhut–Currier
reaction (dimerization). α,β-Unsaturated
thioesters are
intermediates in
several enzymatic processes. Two
prominent examples...
-
Thioester containing protein 1,
often called TEP1 is a key
component of the
arthropod innate immune system. TEP1 was
first identified as a key immunity...
-
First benzoate is
ligated to
CoASH to form the high-energy benzoyl-CoA
thioester. This
reaction is
catalyzed by the HXM-A and HXM-B medium-chain acid:CoA...
-
derivatives of acyl chlorides,
chloroformates and phosgene,
carbonate esters,
thioesters, lactones, lactams, hydroxamates, and isocyanates.
Examples of inorganic...
- many
other coupling partners are viable. In
addition to
alkyl and aryl
thioesters; (hetero)aryl sulfides, thioamides,
sulfanyl alkynes, and thiocyanates...
-
conformational change cause thioester hydrolysis and
release coenzyme A. This
ensures that the
energy released from the
thioester bond
cleavage will drive...
-
familiar odor is due to sulfur-containing
compounds known as S-methyl
thioesters. The same
bacterium is emplo**** to
ferment several washed-rind and smear-ripened...
