- (from
Ancient Gr**** θεῖον (theion) 'sulfur'; also
known as
thiones or
thiocarbonyls) are
organosulfur compounds related to
conventional ketones in which...
- nasturtiums, and capers. The S-oxides of
thiocarbonyl compounds are
known as
thiocarbonyl S-oxides: (R2C=S=O, and
thiocarbonyl S,S-dioxides or sulfenes, R2C=SO2)...
-
fluorination of the
dimer and then
cracking is the prin****l
route to
thiocarbonyl fluoride.
Thiophosgene decomposes at 200 °C or
above to form
carbon disulfide...
-
thionoester fission, as in a
total synthesis of azadirachtin:
Other thiocarbonyl reagents can
replace the
thioacyl chloride. In one
variation the reagent...
- (Z)-propanethial S-oxide), a
member of a
class of
organosulfur compounds known as
thiocarbonyl S-oxides (formerly "sulfines"), is a
volatile liquid that acts as a lachrymatory...
- An
ylide (/ˈɪlaɪd/) or ylid (/ˈɪlɪd/) is a
neutral dipolar molecule containing a
formally negatively charged atom (usually a carbanion)
directly attached...
- the
faster the
carbonyl group will be
converted into the
corresponding thiocarbonyl by Lawesson's reagent. The
chemistry of Lawesson's
reagent and related...
-
source material,
carbon monosulfide, is unstable. Thus, the
synthesis of
thiocarbonyl complexes requires indirect routes, such as the
reaction of disodium...
-
Thiobenzoic acid (benzothioic S-acid)
Carbothioic O-acid RC=SOH hydroxy(
thiocarbonyl)- -thioic O-acid
Thioester Thiolester RC=OSR' S-alkyl-alkane-thioate...
- CSN3 core of the
molecule is
planar as are the
three H's
nearest the
thiocarbonyl group.
Thiosemicarbazides are
precursors to thiosemicarbazones. They...