- In
organic chemistry,
thioesters are
organosulfur compounds with the
molecular structure R−C(=O)−S−R’. They are
analogous to
carboxylate esters (R−C(=O)−O−R’)...
- RC=OSR' S-alkyl-alkane-
thioate S-methyl
thioacrylate (S-methyl prop-2-enethioate)
Thionoester RC=SOR' O-alkyl-alkane-
thioate Dithiocarboxylic acid Carbodithioic...
-
annually by the
reaction of
phosphorus pentasulfide with alcohols.
Phosphoryl thioates are
thermodynamically much
stabler than thiophosphates,
which can rearrange...
-
Protein engineering is the
process of
developing useful or
valuable proteins through the
design and
production of
unnatural polypeptides,
often by altering...
- Salt that is a metal-
thioate/O-esters of dithiocarbonate...
-
tellurite ion is
kinetically inert, but TeO2
equivalents will
oxidize thioates in acid to the
diacyl disulfide. Paratellurite, α-TeO2,
converts at high...
-
cyclohexanecarbothioate and s-tert-butyl 3α,7α,12α-trihydroxy-5β-cholane-24-
thioate".
Organic Syntheses. 7: 87. doi:10.1002/0471264180.os061.28. ISBN 0471264229...
- synthesis.
Electrochemical reduction typically converts thiocyanates to
thioates and cyanide,
although sometimes it can
replace the
thiocyanate group as...
- 4
compared with 4.72 for
acetic acid.
Alkylation of the
corresponding thioate ion
gives a thioester. The
conjugate base of
thioacetic acid, thioacetate...
-
through many
comparable approaches,
usually by
alkylating a free phosphorus-
thioate anion or
thioic acid. They are
conceptually derived from the inorganic...