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Tetramethyltin is an
organometallic compound with the
formula (CH3)4Sn. This liquid, one of the
simplest organotin compounds, is
useful for transition-metal...
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molecular weight and its
chemical shifts are
referenced against tetramethyltin (SnMe 4). Of the
stable isotopes, tin-115 has a high
neutron capture...
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energy of 49 kcal/mol (204 kJ/mol). For
comparison the C–Sn bond in
tetramethyltin is 214 pm long with
dissociation energy 71 kcal/mol (297 kJ/mol). The...
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carbonyl (C=O) of
ketones and aldehyde.:
Milder methylating agents include tetramethyltin, dimethylzinc, and trimethylaluminium.
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prepared by many routes, a
typical method is the
reaction of Re2O7 and
tetramethyltin: Re2O7 + (CH3)4Sn → CH3ReO3 + (CH3)3SnOReO3
Analogous alkyl and aryl...
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Trimethyltin chloride can be
prepared by the
redistribution reaction of
tetramethyltin with tin tetrachloride. SnCl4 + 3 Sn(CH3)4 → 4 (CH3)3SnCl This redistribution...
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Hexamethyldisilane Related compounds Neopentane Tetramethylgermane Tetramethyltin Tetramethyllead Except where otherwise noted, data are
given for materials...
- A
Stille reaction variation:
coupling of
phenyliodide and
tetramethyltin...
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appearance of the dark blue coloration: 2Re2O7 → 4ReO2 + 3O2
Using tetramethyltin, it
converts to
methylrhenium trioxide ("MTO"), a
catalyst for oxidations:...
- many routes, a
typical method is the
reaction of
rhenium heptoxide and
tetramethyltin: Re2O7 + (CH3)4Sn → CH3ReO3 + (CH3)3Sn−O−ReO3
Analogous alkyl and aryl...
