- In
contrast to the
other tetrahalides of titanium, it
adopts a
polymeric structure. In
common with the
other tetrahalides, TiF4 is a
strong Lewis acid...
-
saturated alkyl derivatives, the alkanes,
particularly inert.
Carbon forms tetrahalides with all the halogens.
Carbon also
forms many
oxides such as
carbon monoxide...
-
complexes like SiBr4,
along with
tetrahalides of
germanium (Ge) and tin (Sn), are
Lewis acids.
Although silicon tetrahalides obey the
octet rule, they add...
-
halflife of days at room temperature. It is the most
stable of the
diboron tetrahalides, and does not
appreciably decompose under standard conditions. Diboron...
-
tetrachlorides of
titanium react to give a
statistical mixture of the
mixed tetrahalides, TiBr4−xClx (x = 0-4). The
mechanism of this
redistribution reaction...
-
complexes with
incompletely filled d-s**** are
often tetrahedral, e.g. the
tetrahalides of iron(II), cobalt(II), and nickel(II). In the gas phase, a
single water...
- and
arylsulfur pentafluorides, RSF5. Less well
known are
dialkylsulfur tetrahalides,
mainly represented by the tetrafluorides, e.g., R2SF4.
Compounds with...
- sulfur,
germanium compounds form
salts known as thiogermanates. Four
tetrahalides are known.
Under normal conditions germanium tetraiodide (GeI4) is a...
- Gordon, M. S. (1999). "Intermolecular Self-Interactions of the
Titanium Tetrahalides TiX4 (X = F, Cl, Br)". J. Am. Chem. Soc. 121 (11): 2552–2560. Bibcode:1999JAChS...
-
bioctahedral structures. One
example is
niobium pentachloride.
Metal tetrahalides often exist as
polymers with edge-sharing octahedra.
Zirconium tetrachloride...
