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Tetracobalt dodecacarbonyl is the
chemical compound with the
formula Co4(CO)12. It is a
black crystalline compound that is
insoluble in
water and easily...
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formed in
nickel distillation as a by-product, but it
decomposes to
tetracobalt dodecacarbonyl at the
reaction temperature to give a non-volatile solid...
- [Co(C5H5N)6][Co(CO)4]2 + 8 CO
Heating causes decarbonylation and
formation of
tetracobalt dodecacarbonyl: 2 Co2(CO)8 → Co4(CO)12 + 4 CO Like many
metal carbonyls...
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Other names tetrakis[μ-(acetato-κO:κO')]tetra-μ3-oxotetrakis(pyridine)
tetracobalt Identifiers CAS
Number 209162-45-8
Properties Chemical formula C28H32Co4N4O12...
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structure is
related to that of
methylidynetricobaltnonacarbonyl and
tetracobalt dodecacarbonyl,
which are also tetrahedranes.
These complexes are intermediates...
- Kauffman,
George B. (1992). "Resolution of the Dodecaamminehexa-μ-Hydroxo-
Tetracobalt(III) Ion".
Inorganic Syntheses. Vol. 29. pp. 169–174. doi:10.1002/9780470132609...
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Lawrence F. (1966). "Molecular
Structures of
Triiron Dodecacarbonyl and
Tetracobalt Dodecacarbonyl".
Journal of the
American Chemical Society. 88 (8): 1821–1822...
- P304+P340, P312, P322, P330, P363, P501
Related compounds Other cations Tetracobalt dodecacarbonyl,
Tetrairidium dodecacarbonyl Related compounds Rhodium(III)...
- (ktenasite: IMA15-K, IMA1991-026) 7.DD.80 [300] [301] [302] (IUPAC:
sodium tetracobalt chloro sulfate hexahydroxide hexahydrate)
Thermaerogenite (spinel: IMA2018-021)...
