-
Terpyridine (2,2';6',2"-terpyridine,
often abbreviated to
Terpy or Tpy) is a
heterocyclic compound derived from pyridine. It is a
white solid that is...
-
conversion of
ammine complexes into
nitrosyl complexes: H2O + [Ru(
terpy)(bipy)(NH3)]+ → [Ru(
terpy)(bipy)(NO)]2+ + 5 H+ + 6 e− In some
ammine complexes, the N–H...
-
trichloride is the
coordination complex with the
formula RuCl3(
terpy),
where terpy is terpyridine. It is a
brown paramagnetic solid that is a precursor...
- O−SO2− 2 S−O2− 3
monoanionic monodentate ambidentate 2,2';6',2″-Terpyridine (
terpy) NC5H4−C5H3N−C5H4N
neutral tridentate meridional bonding only Triazacyclononane...
- the
ammonia ligand can be
oxidized to nitrosyl: H2O + [Ru(
terpy)(bipy)(NH3)]+ → [Ru(
terpy)(bipy)(NO)]2+ + 5 H+ + 6 e− An
important reaction is the acid/base...
- response,
notably "triscarboxy-ruthenium terpyridine" [Ru(4,4',4"-(COOH)3-
terpy)(NCS)3],
which is
efficient right into the low-frequency
range of red and...
-
coplanar coordination sites. The most
famous such
ligand is
terpyridine (“
terpy”).
Terpy and its
relatives lack the
steric bulk of the two
terminal donor sites...
- the O 2 -Evolving
Reaction Catalyzed by [(
terpy)(H 2 O)Mn III (O) 2 Mn IV (OH 2 )(
terpy)](NO 3 ) 3 (
terpy = 2,2':6,2' '-Terpyridine)".
Journal of the...
- example, terpyridine,
which is a
tridentate ligand forms the
complex [Zn(
terpy)Cl2].
Another example would involve a
tripodal ligand such as Tris(2-aminoethyl)amine...
- can be
crystallized with 2,2':6',2-terpyridine (
terpy) in dry
acetonitrile to
obtain colorless [Lu(
terpy)(NO3)3], in
which the
nitrogen atom and the oxygen...
