Definition of Tautomerisation. Meaning of Tautomerisation. Synonyms of Tautomerisation

- In chemistry, tautomers (/ˈtɔːtəmər/) are structural isomers (constitutional isomers) of chemical compounds that readily interconvert. The chemical reaction...
- molecular tautomerisation has a forbidden 1-3 suprafacial transition state and therefore has a high energy barrier for this tautomerisation, which was...
- reaction occurs in two stages consisting of three steps: Transimination, Tautomerisation and Hydolysis. In the first stage, alpha amino group of the aminoacid...
- process: 1. Under basic conditions, the ketone undergoes keto-enol tautomerisation. The enolate undergoes electrophilic attack by the hypohalite (containing...
- carboxylic acids), with a pKa of 3.58. Acetoacetic acid displays keto-enol tautomerisation, with the enol form being partially stabilised by extended conjugation...
- vinyl alcohol to acetaldehyde rearrangement is the only keto-enol tautomerisation to have been detected in deep space, induced by the provision of secondary...
- an imine, the internal hydrogen bond is even stronger. In addition, tautomerisation further increases the stability of the compound. The internal hydrogen...
- spontaneously decay via tautomerisation to acetylene, with an energy barrier of between 4 and 21 kJ mol−1. Besides tautomerisation, methylidenecarbene can...
- Alejandro (2010). "The catalytic effect of water on the keto-enol tautomerisation reaction of thioformic acid". Molecular Physics. 108 (10): 1375–1384...
- unlike ethylene, disilene is kinetically unstable with respect to tautomerisation. Disilene has two other tautomers, that are very close in energy: (μ2-H)disilene...