Definition of TMSOTf. Meaning of TMSOTf. Synonyms of TMSOTf

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Definition of TMSOTf

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Meaning of TMSOTf from wikipedia

- Trimethylsilyl trifluoromethanesulfonate (TMSOTf) is an organosilicon compound with the formula (CH3)3SiO3SCF3. It is a colorless moisture-sensitive liquid...
- epicatechin-(4β-8)-catechin-(4α-8)-epicatechin trimer derivatives) can be achieved with TMSOTf-catalyzed condensation reaction, in excellent yields. The structure of benzylated...
- cyanide, trimethylsilyl azide, and trimethylsilyl trifluoromethanesulfonate (TMSOTf). These compounds are produced by a salt metathesis reaction between trimethylsilyl...
- Trimethylsilyl chloride (TMSCl) or trimethylsilyl trifluoromethanesulfonate (TMSOTf) and base (i.e. pyridine, triethylamine, or 2,6-lutidine) in dichloromethane...
- although other polar solvents are also common. Workup of reactions employing TMSOTf involves treatment with an ice-cold solution of sodium bicarbonate and extraction...
- is further reacted with trimethylsilyl trifluoromethanesulfonate (TMSOTf) under the silyl-Hilbert–Johnson reaction and deprotected by an acid or...
- for glycosylation reactions using trichloroacetimidates are BF 3•OEt 2 or TMSOTf. Column chromatographic purification of the reaction mixture can sometimes...
- epicatechin-(4β-8)-catechin-(4α-8)-epicatechin trimer derivatives) can be achieved with TMSOTf-catalyzed condensation reaction, in excellent yields. The structure of benzylated...
- tosylation (TsCl, DMAP) to 24, deprotection to diol (TBAF) and reprotection (TMSOTf, 2,6-lutidine, DIPEA) as TMS ether 25, Ley oxidation to aldehyde 26, cyanohydrin...