- Me3SiCl or
TMSCl. It is a
colourless volatile liquid that is
stable in the
absence of water. It is
widely used in
organic chemistry.
TMSCl is prepared...
-
cyanoborohydride is
often done in the
presence of
trimethylsilyl chloride, or
TMSCl.
Sodium cyanoborohydride can be
purchased from most
chemical suppliers....
-
pyridine in
dichloromethane HBr and
acetic acid at 70 °C
Refluxing with
TMSCl,
sodium iodide and
acetonitrile Reduction with SmI2
Reduction with Red-Al...
-
chloride (
TMSCl) or
trimethylsilyl trifluoromethanesulfonate (TMSOTf) and base (i.e. pyridine, triethylamine, or 2,6-lutidine) in
dichloromethane TMSCl and...
- very
efficient and
replaced TMSCl reagent.
Silylation of
glutamic acid with
excess hexamethyldisilazane and
catalytic TMSCl in
either refluxing xylene...
- with a
covalent M-O(SO2CF3) bond, the by-product
being the
highly volatile TMSCl which is
easily removed.
Joseph Sweeney;
Gemma Perkins;
Enrique Aguilar;...
-
anion equivalents with
silyl halides (typically
trimethylsilyl chloride,
tmsCl).
Silylation of 2-lithio-1,3-dithiane,
followed by
hydrolysis of the dithioacetal...
- IrCl(CO)(PPh3)2 + CH2=C(CH2Cl)(CH2tms) → η4-[C(CH2)3]IrCl(PPh3)(CO) +
tmsCl + PPh3 (Ph = C6H5)
According to gas
phase electron diffraction, η4-C(CH2)3]Fe(CO)3...
-
demonstrated by Evans, is to
silylate the
aldol adduct. A
silicon reagent such as
TMSCl is
added in the reaction,
which replaces the
metal on the alkoxide, allowing...
- step
involves addition of
ethylene glycol and
trimethylsilyl chloride (
TMSCl) in CH2Cl2 solvent.
Addition of TBAF in THF
solvent removes the
silyl protecting...
