Definition of TMEDA. Meaning of TMEDA. Synonyms of TMEDA

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Definition of TMEDA

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Meaning of TMEDA from wikipedia

- Tetramethylethylenediamine (TMEDA or TEMED) is a chemical compound with the formula (CH3)2NCH2CH2N(CH3)2. This species is derived from ethylenediamine...
- is around 11 kcal/mol. TMEDA can also chelate to the lithium cations in n-butyllithium and form solvated dimers such as [(TMEDA) LiBu-n)]2. Phenyllithium...
- of which is dilithioferrocene. Fe(C5H5)2 + 2 LiC4H9 + 2 TMEDA → 2 C4H10 + Fe(C5H4Li)2(TMEDA)2 Schlosser's base is a superbase produced by treating butyllithium...
- conducted in the presence of tetramethylethylenediamine (tmeda). The adduct [Fe(C5H4Li)2]3(tmeda)2 has been crystallized from such solutions. Recrystallization...
- reaction with tetramethylethylenediamine (tmeda): [Ni(CH3COCHCOCH3)2]3 + 3 tmeda → 3 Ni(CH3COCHCOCH3)2(tmeda) Ni(acac)2(H2O)2 reacts quickly in high yield...
- like dimethoxyethane (DME) or ligands like tetramethylethylenediamine (TMEDA). As an exception to the duet rule, a two-coordinate lithate complex with...
- complexes. It is prepared from the tmeda adduct of nickel(II) acetylacetonate by reaction with methyl lithium. The tmeda ligand is easily displaced by bases...
- Structure of the lithium enolate PhC(OLi)=CMe2(tmeda) dimer. H atoms omitted on the diamine....
- tetraethylammonium tetrachloromagnesate [N(CH2CH3)4]2[MgCl4]. The adduct MgCl2(TMEDA) is another. In the coordination polymer with the formula MgCl2(dioxane)2...
- crystals of [(tmeda)Cu-[Hg(CN)2]2][HgCl4] form upon treating CuCl2, the soft Lewis acid Hg(CN)2, and N,N,N',N'-tetramethylethylenediamine (TMEDA). The migration...