Definition of TBSCl. Meaning of TBSCl. Synonyms of TBSCl

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Definition of TBSCl

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Meaning of TBSCl from wikipedia

- with the formula (Me3C)Me2SiCl (Me = CH3). It is commonly abbreviated as TBSCl or TBDMSCl. It is a chlorosilane containing two methyl groups and a tert-butyl...
- anion and 2. the insolubility of the monoanion. At the initial addition of TBSCl, there is only a minor amount of monoanion in solution with the rest being...
- protection of the primary alcohol group to a (t-butyldimethyl) TBS silyl ether (TBSCl / imidazole) and that of the secondary alcohol group with a (Bn) benzyl...
- organic reduction (sodium borohydride) to alcohol 9, alcohol protection (TBSCl, Et3N) to TBS ether 10, hydrazone formation (H2NNHTs) to 11 and finally...
- with the desired organosilicon source (usually a chloride or triflate e.g. TBSCl or TBSOTf). As illustrated by the synthetic examples below, silyl enol ethers...