- were
first described by
George A. Olah.
Superelectrophiles form as a
doubly electron deficient superelectrophile by
protosolvation of a
cationic electrophile...
- Gilbert;
Douglas A.
Klumpp (2007). "Knorr
Cyclizations and
Distonic Superelectrophiles". J. Org. Chem. 72 (25): 9761–9764. doi:10.1021/jo7013092. PMID 17999519...
-
conventional source of "electrophilic fluorine", i.e. the
equivalent to the
superelectrophile F+, is
gaseous fluorine,
which requires specialised equipment for...
- Pictet−Spengler
Reactions Catalyzed by Superacids.
Involvement of
Dicationic Superelectrophiles". J. Org. Chem. 64 (2): 611–617. doi:10.1021/jo982019e. Quevedo, R...
-
Wiley & Sons. p. 509. ISBN 9780471148777. Olah,
George A. (1993). "
Superelectrophiles". Angew. Chem. Int. Ed. Engl. 32 (6): 767–788. doi:10.1002/anie.199307673...
- 1002/anie.198913211. Olah,
George A.; Klumpp,
Douglas A. (2008).
Superelectrophiles and
their Chemistry. John Wiley. ISBN 9780470049617. Liu, J.; Tsong...
-
theoretical calculations favors an O,O-dicationic
intermediate (a
superelectrophile) over the N,O
dicationic intermediate . For
preparative purposes triflic...
- Gilbert;
Douglas A.
Klumpp (2007). "Knorr
Cyclizations and
Distonic Superelectrophiles". J. Org. Chem. 72 (25): 9761–9764. doi:10.1021/jo7013092. PMID 17999519...
- 1063/1.1749219. Olah,
George A.; Klumpp,
Douglas A. (3
January 2008).
Superelectrophiles and
Their Chemistry. John
Wiley & Sons. p. 12. ISBN 9780470185117...
- Ar+ + M → ArM+ + e−; M+ + Ar → ArM+.
Doubly charged cations,
called superelectrophiles, are
capable of
reacting with argon. Ions
produced include ArCF2+...