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Sulfolene, or
butadiene sulfone is a
cyclic organic chemical with a
sulfone functional group. It is a white, odorless, crystalline,
indefinitely storable...
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butadiene to
react with
sulfur dioxide via a
cheletropic reaction to give
sulfolene. This was then
hydrogenated using Raney nickel as a
catalyst to give sulfolane...
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thermodynamic control (≥ -40 °C), the
reaction produces the
corresponding sulfolene through a
cheletropic reaction. The
activation enthalpy for the hetero-Diels–Alder...
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dioxide to buta-1,3-diene
followed by
hydrogenation of the
resulting sulfolene.
Sulfones are
prepared under conditions used for Friedel–Crafts reactions...
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adiponitrile to hexamethylenediamine;
Olefins to paraffins, for example,
sulfolene to sulfolane;
Acetylenes to paraffins, for example, 1,4-butynediol to...
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positional isomers of pentadiene.
Piperylene is a
typical diene. It
forms a
sulfolene upon
treatment with
sulfur dioxide.
Piperylene is the
product of the decarboxylation...
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undergoes a
variety of
cycloaddition reactions. For example, it
forms a
sulfolene upon
treatment with
sulfur dioxide.
Pentadienyl refers to the organic...
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strain on the
formation and
pyrolysis of some Diels–Alder
adducts of 2-
sulfolene (2,3-dihydrothiophene 1,1-dioxide) and
maleic anhydride with 1,3-dienes...
- It can be
produced by the retro-Diels-Alder
reaction of cyclohexene.
Sulfolene is a
convenient solid storable source for 1,3-butadiene in the laboratory...
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deoxygenated yielding 2,3-dibromnaphthalene. The
endoxide reacts with 3-
sulfolene in a Diels-Alder
reaction upon
elimination of
sulfur dioxide. The resulting...