- N-Sulfinyl
imines (N-sulfinylimines,
sulfinimines,
thiooxime S-oxides) are a
class of
imines bearing a
sulfinyl group attached to nitrogen.
These imines...
-
organozinc compounds,
organolithium compounds, and enolates.
Chiral sulfinimines as
intermediates for the
asymmetric synthesis of
amines have also been...
- S. (December 1994). "Asymmetric
strecker synthesis using enantiopure sulfinimines: A
convenient synthesis of α-amino acids".
Tetrahedron Letters. 35 (50):...
- J. M.; Zhang, Y.; Reddy, G. V.; Burns, D. M.; Davis, F. A. (2000). "
SULFINIMINES (THIOOXIMINE S-OXIDES):
ASYMMETRIC SYNTHESIS OF
METHYL (R)-(+)-β-PHENYLALANATE...
- as thioethers) can be
aminated with hydroxylamine-O-sulfonic acid to
sulfinimines (isosteric with
sulfoxides but far more unstable) or
phosphorus compounds...
- 3-Amino
Alcohol Derivatives Through an
Asymmetric Aldol-Tishchenko
Reaction of
Sulfinimines".
Organic Syntheses. 94: 259–279. doi:10.15227/orgsyn.094.0259....
- (2012). "Enantioselective
Synthesis of
Cocaine C-1
Analogues using Sulfinimines (N-Sulfinyl Imines)". The
Journal of
Organic Chemistry. 77 (5): 2345–2359...
- Davis,
Franklin A.; et al. (2005-08-23). "Asymmetric
Synthesis Using Sulfinimines (N-Sulfinyl Imines)". ChemInform. 36 (34). doi:10.1002/chin.200534036...
- α-Amino
Phosphonic Acids via the
Addition of
Phosphites to
Enantiopure Sulfinimines". The
Journal of
Organic Chemistry. 62 (22): 7532–7533. doi:10.1021/jo971394o...
-
forming a
hemiaminal intermediate. The
intermediate then
fragments into a
sulfinimine, and,
after protonation, the
desired α-hydroxyketone or α-hydroxyester...
