- In
organosulfur chemistry,
sulfinamide is a
functional group with the
structure R−S(O)−NR2 (where R =
alkyl or aryl). This
functionality is
composed of...
-
organic synthesis. The
related sulfinamides (R(S=O)NHR) are
amides of
sulfinic acids (R(S=O)OH) (see sulfinyl).
Chiral sulfinamides such as tert-butanesulfinamide...
- 2-methyl-2-propanesulfinamide or Ellman's
sulfinamide) is an
organosulfur compound and a
member of the
class of
sulfinamides. Both
enantiomeric forms are commercially...
- Yuanjing; Zhang,
Junliang (2020). "Stereoselective
Synthesis of
Chiral Sulfinamide Monophosphine Ligands (Ming-Phos)(S, Rs)-M".
Organic Syntheses. 97: 262–273...
-
towards nucleophiles,
including thiols. The
initial adduct rearranges to a
sulfinamide: HNO + RSH → RS(O)NH2 In
biological samples,
nitroxyl can be detected...
-
pseudoephedrine amides into
synthetically useful functional groups This
specific sulfinamide chiral auxiliary was
initially developed by
Jonathan A. Ellman, and its...
- the acid
strength and
stability diminish in that order. Sulfonamides,
sulfinamides and sulfenamides, with
formulas R−SO2NR′2, R−S(O)NR′2, and R−SNR′2, respectively...
- condensation. Many
sulfinamides are
commercially available in both (R)- and (S)-forms. The two most
commonly used are the
Davis p-toluene-
sulfinamide and the Ellman...
-
useful intermediates for
preparation of
other sufinyl derivatives such as
sulfinamides, sulfinates, sulfoxides, and thiosulfinates.
Unlike the
sulfur atom in...
- Yuanjing; Zhang,
Junliang (2020). "Stereoselective
Synthesis of
Chiral Sulfinamide Monophosphine Ligands (Ming-Phos)(S, Rs)-M".
Organic Syntheses. 97: 262–273...
