- chloride, CH3SCl.
Sulfenate esters have the
formula RSOR′. They
arise by the
reaction of
sulfenyl chlorides on alcohols.
Sulfenate esters are intermediates...
- } an
alkyl sulfenate + 2-aminoacrylate Hence, this
enzyme has one substrate, S-alkyl-L-cysteine S-oxide, and two products,
alkyl sulfenate and 2-aminoacrylate...
- have
however been
prepared by
reaction of
phosphites with
benzene alkyl sulfenates: P(OR)3 + 2 ROSC6H5 → P(OR)5 + (SC6H5)2
Phosphoranes of the type R3P=CR2...
- Saucy–Marbet rearrangement) give
allene aldehydes,
while propargylic sulfenates 6 give
allene sulfoxides.
Allenes can also be
prepared by nucleophilic...
-
alcohol with an aryl
sulfide in the
presence of triethylamine. Initially, a
sulfenate ester is
formed followed by a [2,3]-sigmatropic
rearrangement to afford...
-
sulfoxide 1
which undergoes a
thermal 2,3-sigmatropic
rearrangement to give a
sulfenate ester 2. This can be
cleaved using a thiophile, such as
phosphite ester...
-
Methanesulfenyl Chloride with
Alkoxides and Alcohols.
Preparation of
Aliphatic Sulfenate and
Sulfinate Esters". J. Org. Chem. 31 (11): 3587–3592. doi:10.1021/jo01349a027...
- Alan M. (1982). "Synthesis of a
chiral O-bound
sulfoxide from an S-bound
sulfenate ion".
Journal of the
American Chemical Society. 104: 137–141. doi:10.1021/ja00365a026...
