- In
organosulfur chemistry,
sulfenamides (also
spelled sulphenamides) are a
class of
organosulfur compounds characterized by the
general formula R−S−N(−R)2...
-
intermediate in
synthesis of
other organic compounds. It is the
precursor to
sulfenamide-based
reagents used as
accelerators for vulcanization. The
amine itself...
- S2CID 115671283. Ducháček, Vratislav; Kuta, Antonín (October 1986). "Long-time
sulfenamide-accelerated
sulfur vulcanization of
natural rubber/chlorobutyl rubber...
-
accelerating and
mostly consist of thiazoles,
often derivatised with
sulfenamide groups. The prin****l
compound is 2-mercaptobenzothiazole (MBT), which...
-
transformations in
organic synthesis.
Silver acetate is used to
prepare sulfenamides from
disulfides and
secondary amines: R2NH +
AgOAc + (RS)2 → R2NSR +...
- both
enantiomers are
converted to
achiral products (sulfenic acid and
sulfenamide configurations)
which react with a
cysteine group in H+/K+ ATPase, thereby...
- residues.
After being activated by
gastric (stomach) acid to a
reactive sulfenamide intermediate,
rabeprazole permanently binds the
cysteine residues, forming...
- S-nitrosotriphenylmethanethiol (Ph3CSNO),
tritylsulfenyl chloride (Ph3CSCl), and
trityl sulfenamide (Ph3CSNH2).
Tetraphenylmethane Triphenylmethanol Triphenylmethyl chloride...
- tert-Butylamine is used as an
intermediate in the
preparation of the
sulfenamides such as N-tert-butyl-2-benzothiazylsulfenamide and...
-
cysteines accessible from the
luminar surface of the enzyme, a
tetracyclic sulfenamide. This is a
planar molecule thus any
enantiomer of a PPI
loses stereospecifity...
