- name for
asymmetrical three-center two-electron bonds. The
first stable subvalent Be
complex ever
observed contains a three-center two-electron π-bond that...
- Schilling,
Birgitte E. R.; Lappert,
Michael F.; Thorne,
Andrew J. (1986). "
Subvalent Group 4B
Metal Alkyls and Amides. Part 8.
Germanium and Tin
Carbene Analogues...
-
About the
surprising system Ga+/HSiR3/olefin,
proof of
oxidation with
subvalent Ga+ and
silylium catalysis with
perfluoroalkoxyaluminate anions". Chemical...
- Klaus; Peringer, Paul (1997). "Synthesis and
crystal structure of the
subvalent mercury cluster [triangulo-Hg3(μ-dmpm)4][O3SCF3]4 (dmpm = Me2PCH2PMe2)"...
- 2.926 Å, c = 24.0888 Å
lustrous black solid,
stable in air; Ni3+ and
subvalent Ag2+ Ag3Ni2O4
hexagonal P63/mmc, a = 2.9331 Å, b = 2.9331 Å, c = 28.31 Å...
-
Birgitte E. R.; Lappert,
Michael F.; Thorne,
Andrew J. (1986-01-01). "
Subvalent Group 4B
metal alkyls and amides. Part 8.
Germanium and tin
carbene analogues...
- addition,
reduction and
reductive coupling: the
versatile reactivity of
subvalent gallium cations".
Dalton Transactions. 50 (42): 15103–15110. doi:10.1039/D1DT02682H...
- (II) chemistry: syntheses, structures,
properties and
applications of
subvalent thallium complexes with alkyl, cyclopentadienyl,
arene or
hydrotris (pyrazolyl)...
-
reacts by
inserting itself into
other bonds.
Reaction with Al2I6
yields subvalent halide species;
reaction with As4tBu4
yields As-Al bonds. When reacted...
- ISBN 9780470682531. Hudson, Andrew; Lapper,
Michael F.; Lednor,
Peter W. (1976). "
Subvalent Group 4B
metal alkyls and amides. Part 4. An
electron spin
resonance study...
