-
Steric effects arise from the
spatial arrangement of atoms. When
atoms come
close together there is
generally a rise in the
energy of the molecule. Steric...
- The
steric factor,
usually denoted ρ, is a
quantity used in
collision theory. Also
called the
probability factor, the
steric factor is
defined as the ratio...
- der
Waals strain is also
called Van der
Waals repulsion and is
related to
steric hindrance. One of the most
common forms of this
strain is
eclipsing hydrogen...
-
variety of
factors including: (1)
metal identity and
electron density, (2)
sterics, (3) parti****ting ligands, (4)
coordination number, (5) geometry, and...
-
ethanol produces the
Zaytsev product with
moderate selectivity. Due to
steric interactions, a
bulky base – such as pot****ium tert-butoxide, triethylamine...
-
formed by its
nonbonding valence electrons is
known as the
central atom's
steric number. The
electron pairs (or
groups if
multiple bonds are present) are...
- form a thin
layer of
calcium stearate,
which functions as a
release agent.
Steric acid can be
converted to zinc stearate,
which is used as a
lubricant for...
- A
sterimol parameter is a set of
vectors which describes the
steric occupancy of a molecule.
First developed by
Verloop in the 1970s.
Sterimol parameters...
- As the name suggests, a non-nucleophilic base is a
sterically hindered organic base that is a poor nucleophile.
Normal bases are also nucleophiles, but...
- form
adducts which exhibit steric effects. For example:
trimethyltin chloride, when
reacting with
diethyl ether,
exhibits steric repulsion between the methyl...
