- In chemistry,
stereospecificity is the
property of a
reaction mechanism that
leads to
different stereoisomeric reaction products from
different stereoisomeric...
- general,
glycerophospholipids use an "sn" notation,
which stands for
stereospecific numbering. When the
letters "sn"
appear in the nomenclature, by convention...
-
demercuration part of the
reaction involves free
radical mechanism and is not
stereospecific, i.e. H and OH may be syn or anti to each other.
Oxymercuration followed...
-
reaction rate of a
chemical reaction.
Stereochemistry is
involved in:
stereospecific reactions stereoselective or
asymmetric reactions racemisation processes...
-
Styrene oxide is an
epoxide derived from styrene. It can be
prepared by
epoxidation of
styrene with
peroxybenzoic acid, in the
Prilezhaev reaction: Styrene...
-
General structures of mono-, di-, and tri-acylglycerides with
names according to the
stereospecific numbering...
- ring).
Cortisone is
converted back to the
active steroid cortisol by
stereospecific hydrogenation at
carbon 11 by the
enzyme 11β-Hydroxysteroid dehydrogenase...
- to the more
substituted carbon.
Alkene oxymercuration-demercuration
Stereospecific: Can only be anti
addition –
water kicks out the
mercury from underneath...
- phosphite,
which then decarboxylates. The Corey-Winter
olefination is a
stereospecific reaction: a trans-diol
gives a trans-alkene,
while a cis-diol gives...
- of the
double bond is
preserved in the
product and the
reaction is
stereospecific. Thus, cyclohexene, diiodomethane, and a zinc-copper
couple (as iodomethylzinc...
