- In chemistry,
stereoselectivity is the
property of a
chemical reaction in
which a
single reactant forms an
unequal mixture of
stereoisomers during a non-stereospecific...
- and
remove the auxiliary. However, in some
cases the only
available stereoselective methodology relies on
chiral auxiliaries and
these reactions tend to...
- reaction.
Stereochemistry is
involved in:
stereospecific reactions stereoselective or
asymmetric reactions racemisation processes Carey,
Francis A.; Sundberg...
-
trichloroacetimidate to
encourage B
stereoselectivity through the
gauche effect. This
reasonable stereoselectivity is
clear through visualization of the...
- The
addition of HMPA is
known to
reverse the
stereoselectivity of deprotonation. The
stereoselective formation of
enolates has been
rationalized with...
-
synthetic routes that can be
completed including total synthesis,
stereoselective synthesis,
automated synthesis, and many more. Additionally, in understanding...
- "Samarium-catalyzed
intramolecular Tishchenko reduction of β-hydroxy ketones. A
stereoselective approach to the
synthesis of
differentiated anti 1,3-diol monoesters"...
- L-proline
amide hydrolase (EC 3.5.1.101, S-
stereoselective piperazine-2-tert-butylcarboxamide hydrolase, LaaA, L-amino acid amidase) is an
enzyme with...
- Fürst-Plattner rule (also
known as the trans-diaxial effect)
describes the
stereoselective addition of
nucleophiles to
cyclohexene derivatives.
Cyclohexene derivatives...
-
operates on only one (or a subset) of the stereoisomers. In contrast,
stereoselectivity is the
property of a
reactant mixture where a non-stereospecific mechanism...
