- In chemistry,
stereoselectivity is the
property of a
chemical reaction in
which a
single reactant forms an
unequal mixture of
stereoisomers during a non-stereospecific...
- and
remove the auxiliary. However, in some
cases the only
available stereoselective methodology relies on
chiral auxiliaries and
these reactions tend to...
-
synthetic routes that can be
completed including total synthesis,
stereoselective synthesis,
automated synthesis, and many more. Additionally, in understanding...
-
trichloroacetimidate to
encourage B
stereoselectivity through the
gauche effect. This
reasonable stereoselectivity is
clear through visualization of the...
- He is a two-time
Nobel laureate in
Chemistry known for his work on
stereoselective reactions and
click chemistry.
Sharpless was
awarded half of the 2001...
- reaction.
Stereochemistry is
involved in:
stereospecific reactions stereoselective or
asymmetric reactions racemisation processes Carey,
Francis A.; Sundberg...
-
operates on only one (or a subset) of the stereoisomers. In contrast,
stereoselectivity is the
property of a
reactant mixture where a non-stereospecific mechanism...
- 133. ISBN 0-387-95468-6. Molander, G. A., ed. (2011).
Stereoselective Synthesis 2:
Stereoselective Reactions of
Carbonyl and
Imino Groups (1 ed.). Stuttgart:...
- Hirschmann, H. (1
October 1960). "The
Nature of
Substrate Asymmetry in
Stereoselective Reactions".
Journal of
Biological Chemistry. 235 (10): 2762–2767. doi:10...
-
functionality is
required on the
catalyst for the
reaction to
proceed stereoselectively.
Chiral α-amino
acids with
various functionalities are conveniently...
