- The Woodward–Hoffmann
rules (or the
pericyclic selection rules) are a set of
rules devised by
Robert Burns Woodward and
Roald Hoffmann to
rationalize or...
- In
organic chemistry, the
Mukaiyama aldol addition is an
organic reaction and a type of
aldol reaction between a
silyl enol
ether (R2C=CR−O−Si(CH3)3) and...
- The
figure below illustrates one of the
commonly accepted models for
stereoselection without any
modification to the
Henry reaction. In this model, stereoselectivity...
- metal-oxygen
bonds "tighten" the
transition state and
effects greater stereoselection.
Boron is
often used
because its bond
lengths are
significantly shorter...
- by
Robert B.
Woodward and
Roald Hoffmann of the Woodward-Hoffmann
stereoselection rules,
which could predict the
reaction rates between two reactants...
-
linearity can be
expressed mathematically, as
shown in
Equation 1.
Stereoselection (i.e. the eeproduct) that is
higher or
lower than the enantiomeric...
- doi:10.1002/cber.19911240136. Bérubé, G.; DesLongchamps, P. (1987). "
Stéréosélection acyclique-1,5: Synthèse de la chaîne latérale
optiquement active de...
-
Clayton H.; Hug,
Kathleen T.; Flippin, Lee A. (1
January 1984). "Acyclic
stereoselection. 27.
Simple diastereoselection in the
lewis acid
mediated reactions...
- ISBN 978-3-527-31161-3. Gridnev, I. D.; Imamoto, T. (2004). "On the
Mechanism of
Stereoselection in Rh-Catalyzed
Asymmetric Hydrogenation: A
General Approach for Predicting...
- Jarvi; P. A. Radel; C. R.
Hadley (1988). "Acyclic
stereoselection. Part 42. 1,4- and 1,5-
Stereoselection by
sequential aldol addition to a .alpha.,.beta...
