- In chemistry,
primarily organic and com****tional chemistry, a
stereoelectronic effect is an
effect on
molecular geometry, reactivity, or
physical properties...
-
traditional bond nor a
steric effect. In
organic chemistry, the term
stereoelectronic effect is also used to
emphasize the
relation between the electronic...
- be
controlled through both
primary and
secondary stereoelectronic effects. The
primary stereoelectronic effect in the Baeyer–Villiger
oxidation refers to...
-
Dunathan stereoelectronic hypothesis is a
concept in
chemistry to
explain the
stereospecefic cleavage of
bonds using pyridoxal phosphate. This
occurs because...
- and a weak base ("soft conditions"): For
deprotonation to occur, the
stereoelectronic requirement is that the alpha-C-H
sigma bond must be able to overlap...
- Edward-Lemieux
effect (after J. T.
Edward and
Raymond Lemieux) is a
stereoelectronic effect that
describes the
tendency of
heteroatomic substituents adjacent...
- determined,
keeping in mind
steric and
stereoelectronic effects (see the
section below for a
discussion of
stereoelectronic effects in
oxocarbenium rings). Once...
- can be enhanced. With the
silicon atom beta to H, a σC-Si → σ*C-H
stereoelectronic effect weakens the C-H bond,
resulting in its
exclusive migration and...
- Baldwin, Jack E.; Kruse,
Lawrence I. (1977). "Rules for ring closure.
Stereoelectronic control in the
endocyclic alkylation of
ketone enolates".
Journal of...
-
subsequently shown that the
increase in
stability is
primarily through stereoelectronic effects and that
hydration of the
hydroxyproline residues provides...
