-
providing stereocontrol such as in the
synthesis of miyakolide.
Reaction classes used in
synthesis of
natural products under the
macrocyclic stereocontrol model...
- form at a
fixed orientation relative to the old. This "substrate-based
stereocontrol" has seen
extensive study and
examples pervade the literature. In many...
-
stereocenters can be
achieved by this
method with a very high
degree of
stereocontrol. (ref?) (1) However,
stoichiometrically relative amounts of metal-containing...
- synthesis,
reaction development,
conformational analysis,
macrocyclic stereocontrol, and com****tional chemistry.
Still and
coworkers also
developed the...
- Cavallo, L. (2004). "Do New
Century Catalysts Unravel the
Mechanism of
Stereocontrol of Old Ziegler–Natta Catalysts?". Acc. Chem. Res. 37 (4): 231–241. doi:10...
- high
flexibility in the metal–ligand
complex is
detrimental for high
stereocontrol. In 1996
Feringa et al.,
reported an
enantioselective 1,4-addition of...
- process.
Because the
reaction is concerted, it
exhibits a high
degree of
stereocontrol, and can be emplo****
early in a
synthetic route to
establish stereochemistry...
-
fundamental contributions that his
research has made to the
areas of
stereocontrol in
organometallic chemistry,
asymmetric synthesis and
total synthesis...
- MacMillan’s
catalyst and Jorgensen's catalysts,
proceed with
excellent stereocontrol.: 5574
Proline catalysis was
initially reported by
groups at Schering...
-
Benzylic activation in tricarbonyl(arene)chromium
complexes refers to the
reactions at the
benzylic position of
aromatic rings complexed to chromium(0)...
