- Stereochemistry, a
subdiscipline of chemistry,
studies the
spatial arrangement of
atoms that form the
structure of
molecules and
their mani****tion. The...
- 1002/anie.200300626. PMID 14694470.
Short Synthesis of
Skeletally and
Stereochemically Diverse Small Molecules by
Coupling Petasis Condensation Reactions...
- 1021/ja00045a027.
Ralph A.
Wheeler and P. N. V.
Pavan Kumar (1992). "
Stereochemically active or
inactive lone pair
electrons in some six-coordinate, group...
- Bennett, M. J.; Jones, C. E.; Smith, R. A.; Graham, W. A. G. (1977). "
Stereochemically Nonrigid Six-Coordinate
Metal Carbonyl Complexes. 1.
Polytopal Rearrangement...
-
advancements in
synthetic methodology,
chemists have been able
synthesize stereochemically selective complex molecules without racemization.
Stereocontrol provides...
- The
geometry is
common for
certain main
group compounds that have a
stereochemically-active lone pair, as
described by
VSEPR theory.
Certain compounds crystallize...
- non-bonding
pairs do not
influence molecular geometry and are said to be
stereochemically inactive. In
molecular orbital theory (fully
delocalized canonical...
-
retains a more
positive character than the
lesser substituted carbon.
Stereochemically,
oxymercuration is an anti addition. As
illustrated by the
second step...
- White, Taber, Trost, ****uyama, Guillou, and Stork.
Because of the
stereochemical complexity and
consequent synthetic challenge presented by this polycyclic...
-
apart from
achiral glycine, but also (3R) at the β-carbon. The full
stereochemical specification is (2S,3R)-L-threonine.
Nonpolar amino acid interactions...