- 1002/anie.200300626. PMID 14694470.
Short Synthesis of
Skeletally and
Stereochemically Diverse Small Molecules by
Coupling Petasis Condensation Reactions...
- not
until after the
observations of
certain molecular phenomena that
stereochemical principles were developed. In 1815, Jean-Baptiste Biot's observation...
- 1021/ja00045a027.
Ralph A.
Wheeler and P. N. V.
Pavan Kumar (1992). "
Stereochemically active or
inactive lone pair
electrons in some six-coordinate, group...
- Bennett, M. J.; Jones, C. E.; Smith, R. A.; Graham, W. A. G. (1977). "
Stereochemically Nonrigid Six-Coordinate
Metal Carbonyl Complexes. 1.
Polytopal Rearrangement...
-
predictions in the
following tables. For main-group elements,
there are
stereochemically active lone
pairs E
whose number can vary
between 0 to 3. Note that...
-
original structure. If present, the
stereochemical layer, with
sublayers b, /t, /m and /s,
gives stereochemical information, and the
isotopic layer /i...
-
shorter and two longer. The
pyramidal nature indicates the
presence of a
stereochemically active lone pair of electrons. When PbO
occurs in
tetragonal lattice...
- The
geometry is
common for
certain main
group compounds that have a
stereochemically-active lone pair, as
described by
VSEPR theory.
Certain compounds crystallize...
-
topological isomers are
molecules with the same
chemical formula and
stereochemical bond
connectivities but
different topologies.
Examples of molecules...
- non-bonding
pairs do not
influence molecular geometry and are said to be
stereochemically inactive. In
molecular orbital theory (fully
delocalized canonical...
